10,11-Dihydro­diindeno[1,2-b:2′,1′-d]thio­phene

نویسندگان

  • Irina Afonina
  • Simon J. Coles
  • Michael B. Hursthouse
  • Alexander Kanibolotsky
  • Peter J. Skabara
چکیده

The title compound, C(18)H(12)S, comprises five fused rings forming an essentially planar mol-ecule, with a total puckering amplitude (Q) of 0.032 Å and a maximum deviation from the mean plane of 0.014 (4) Å for the C atoms of the methyl-ene groups. A crystallographic mirror plane orthogonal to the mol-ecular plane passes through the S atom and the midpoint of the opposite C-C bond within the central five-membered ring. The mol-ecules lie in layers, forming edge-to-face C-H⋯π inter-actions, with a separation of 2.66 Å between one H atom of the methyl-ene group and the centroid of an adjacent indene ring.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2007